This is a type of deterioration which can be linked to corrosion and corrosion control processes. Corrosionpedia what is sulfide stress cracking ssc. The effect of low h2s concentrations on welded steels march. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. In this paper, mechanical performance test, slow strain rate test ssrt and optical microscopy analysis were employed in studying the effect of carbon migration on sulfide stress corrosion cracking sscc behaviors of cr5moa3020cr18ni9 dissimilar joints. Laboratory testing of metals for resistance to sulfide. An increase in the partial pressure of hydrogen sulfide aggravates the catastrophic breakdown of carbon steel, yet diminishes both the corrosion rate and the localization of corrosion attack on aluminum alloys. The blistering damage tends to form parallel to the. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. In stress corrosion cracking, its first cousin, the corrosion process, generally pitting, must start to get the hydrogen generation started. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogen assisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. Nickelchromiummolybdenum alloy hastelloy c2000 specialty among nickel alloys by alloy environmentally assisted cracking or eac refers to the attacks including stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme and corrosion fatigue cf.
Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment. Pdf hydrogen sulfide stress corrosion cracking of high. Hydrogen can assist in the propagation of corrosion fatigue cracks and can also cause sulphide stress corrosion cracking in ferritic and martensitic steels, including the. Hydrogen sulphide these corrosion data are mainly based on results of general corrosion laboratory tests, carried out with pure chemicals and water solutions nearly saturated with air the corrosion rate can be quite different if the solution is free from oxygen. The incubation time for crevice corrosion and pitting in seawater is relatively short, often only a few days. The most common forms of wet h 2 s cracking are hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. The stress corrosion cracking behaviour of uns n08031 in.
Mild steel is a popular structural steel in this industry but is susceptible to surface scale formation and associated corrosive action, the prevention of which requires some. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. We published this article under an openaccess license. Wet hydrogen sulfide h2s cracking inspectioneering. Materials and corrosion trends in offshore and subsea oil. Hydrogen sulfide stress corrosion cracking of high strength steel wire article pdf available in corrosion houston tx 282. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Wet h 2 s cracking can occur in susceptible steels exposed to aqueous environments containing hydrogen sulfide. Effect of hydrogen sulfide on aqueous corrosion of. In this situation, cracking failures can often be thought of as a type of stress corrosion cracking. High temperature hydrogen sulfide corrosion of carbon steel and low chrome alloys has become a serious problem in the petroleum industry in connection with the increasing use of high pressure hydrogenation and dehydrogenation processes for upgrading petroleum fractions. Hydrogen embrittlement and stress corrosion cracking. Hydrogen sulfide is a chemical compound with the formula h 2 s, and is often a colorless gas with a rotten egg odor, commonly referred to as sewer gas.
Stress corrosion cracking behavior of nickel base alloys. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Hydrogen sulfide corrosion and its prevention is an important topic in a range of industrial processes and environments including oil and gas and its related activities. Several mitigation methods are known to prevent sulfide stress cracking and hydrogen induced corrosion. This type of failure is known as stress corrosion cracking, often abbreviated to scc.
The results showed that the resistance to sscc of this joint improved first then decline after 98h aging treatments. H 2 s corrosion, or sour corrosion, occurs when h 2 s gas reacts with carbon steel in a wet and sour environment. S resistant coating to protect pressure vessels from. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Sulfide stress cracking of nickelcontaining lowalloy steels. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
Hydrogen sulfide stress corrosion cracking in materials. Link to corrigendum together with my colleagues and good friends dr. Sulphide stress cracking ssc is the biggest concern 9. The first type is commonly referred to as hydrogen induced cracking hic and can occur where little or no applied or residual tensile stress exists. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism.
Eventually, cracking occurs when several hydrogen blisters connect in the base metal. The manuscript can be downloaded following this link or directly. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Materials and corrosion trends in offshore and subsea oil and gas production. Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. Tm01772016, laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments sorry this product is no longer available testing of metals subjected to tensile stresses for resistance to cracking failure in lowph aqueous environments containing hydrogen sulfide h2s. The corrosionelectrochemical behavior of both carbon steel and aluminum alloys in hydrogen sulfidebearing mineralized media is considered.
Protect aluminum from hydrogen sulfide with nickel plating or electroless nickel offers additional detail on a very similar subject. The incubation time for stress corrosion cracking can be very short, sometimes measured in hours. An extensive failure analysis shows how many service failures occurred in the industry and what kind of alloys and stresses led to initiation and propagation of stress corrosion cracks which caused these service failures. It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism.
The resistance to chlorideinduced stress corrosion cracking of uns n08031 was tested on ubend specimens according to astm g 30 for a testing time of 2000 hours. Sulphide stress corrosion cracking sulphide stress cracking sscc has special importance in gas and oil industry, as the materials being processed there natural gas and crude oil often contain considerable amount of hydrogen sulphide. Aluminum alloys most often associated with stresscorrosion cracking in actual service are 2014, 2024, 2219, 7075, 7079, and 7178 alloys, and cast alloys of ternalloy 7, 40e, 195, and 220 compositions. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Stress corrosion cracking an overview sciencedirect topics. Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of. Jan 08, 2002 material resistance to sulfide stress corrosion cracking is of prime importance for oil and gas industrial applications. To check its resistance to scc and ssc, several tests were performed.
Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. It is generally recognised that the risk of sulphide stress corrosion cracking in ferritic steels increases with hardness, and maximum hardness limits are the basis of guidelines for avoidance of cracking in many standards. It is a form of hydrogenrelated cracking and can have two distinct morphologies. This barcode number lets you verify that youre getting exactly the right version or edition of a book. Effect of carbon migration on sulfide stress corrosion. The results indicate that flow control valve body failed due to combination of hydrogen induced corrosion cracking hicc and sulfide stress corrosion cracking sscc. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. It is a form of hydrogen related cracking and can have two distinct morphologies. Protection of metal from the hydrogen sulfide corrosion. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require. Hydrogen sulfide attack and corrosion of copper electrical. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. The effect of low h2s concentrations on welded steels.
The effect of hydrogen sulfide h 2 s on the corrosion behavior of commercially pure aluminum din al 99. Pdf sulfide stress corrosion cracking and hydrogen induced. Pdf sulfide stress corrosion cracking and hydrogen. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. Damage due to hydrogen embrittlement and stress corrosion.
According to hic and ssc laboratory tests and also with regard to cost of engineering materials, it was evident that the best alternative for the valve body alloy is a217 wc9. It is now well known that ssc is a particular form of hydrogen stress cracking. Hydrogen can assist in the propagation of corrosion fatigue cracks and can also cause sulphide stress corrosion cracking in ferritic and martensitic steels, including the stainless grades. This standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide h 2 s. Sulfide stress corrosion cracking and hydrogen induced. Sep 29, 2014 link to corrigendum together with my colleagues and good friends dr. Sulfide stress corrosion cracking occurs due to conjoint action of chloride and hydrogen sulfide, presence of tensile stresses and nonlinear relationship with temperature. Sulphide stress corrosion cracking sscc laboratory. Sulfide stress cracking mostly occurs in very highly acidic environments. Resistance to corrosion and stress corrosion cracking in hydrogen sulphide environments scanning electron microscopy of cunimnalnb, carried out after exposure in acidified hydrogen sulphide solution at room temperature, reveals that the aluminium content of the material produces an oxide layer which gives the alloy a considerable degree of. Although hydrogeninduced cracking and stress corrosion cracking are similar phenomena, both types of damage are usually described and treated separately. Detection, control, and correction of hydrogen sulfide. Paper 143, corrosion 2000, nace international, orlando, florida, usa, 2631 march 2000.
Sulfide stress cracking is also environmentally produced so you have a delay until the sulfide environment causes hydrogen entry into the metal. Hydrogen sulfide stress corrosion cracking in materials for. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Corrosion inhibitors for systems with a high content of hydrogen sulphide h2s in the produced fluids since the discovery and development of oil and gas fields containing hydrogen sulfide in the production wells, the problem of protection of metal from the hydrogen sulfide corrosion arose acutely. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. Hydrogen sulphide these corrosion data are mainly based on results of general corrosion.
Hydrogen embrittlementsulfide stress cracking h2s metal. Stress corrosion cracking international institute of. Corrosion of metal and concrete is a major issue associated with the generation and oxidation of hydrogen sulfide. An extensive failure analysis shows how many service failures occurred in the industry and what kind of alloys and stresses led to initiation and propagation of stress. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials. Mechanism of sulfide corrosion hydrogen sulfide corrosion can occur by two mechanisms. Alloys which are commercially available and those which have modified metallurgical structures and. High temperature hydrogen sulfide corrosion corrosion. Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Coatings protecting refinery pressure vessels from h 2 s hydrogen sulfide stress cracking ssc there is a need to extract hydrogen sulfide from oil and gas in petrochemical processing. The role of hydrogen in the mechanism of stress corrosion cracking has been known since the 1970s so that preventative measures have since been introduced. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at higher temperatures.
Aluminum alloys that contain appreciable amounts of soluble alloying elements, primarily copper, magnesium, silicon, and zinc, are susceptible to stresscorrosion cracking scc. Corrosion behavior of aluminum alloys in the presence of. If the presence of hydrogen sulfide causes entry of hydrogen into the component, the cracking phenomenon is often termed sulphide stress cracking ssc the use of cathodic protection for corrosion protection if the process is not properly. One is to perform a stressrelieving treatment on the metal to reduce hardness levels to acceptable levels in an annealed microstructure. Stress corrosion cracking the international institute of.